This paper is nice, but it goes over some finer technical things.
So, not about the great wall, but there's projects out there, like this one https://github.com/salesforce/ja3 , which talk about how you can fingerprint fully encrypted traffic(TLS/HTPS). There's a great section in the Readme "How it works" that goes over it. Would be surprising if the great wall doesn't do this, when some open source firewall will.