A suggestion from someone who has built three different CO2 monitors - don't chase the numbers. 420/800/1200 ppm has no meaningful difference, and if you don't have a good way to calibrate your CO2 sensor, such as a pure nitrogen environment or taking your sensor outside at least weekly and forcing a calibration, you can easily be 500 ppm out of true.
I suspect that you probably feel more clear-headed outside because there is wind and nature and distractions that aren't an LED screen.
That said, I think an interesting experiment would be to use a CO2 scrubber to remove carbon dioxide, instead of trying to overpower it with more oxygen. Otherwise, just get a tank of oxygen and face mask and see how it works for you.