A greater partial pressure of oxygen != lesser partial pressure of CO2.
You wouldn't want the room to be 98% O2 though, that's just asking for oxygen toxicity. You wouldn't want CO2 really low either, that's just asking for hypocapnia. So unless you have specialised equipment to control the gas mixture you are breathing, why not just increase ventilation a bit if you'd like to decrease CO2 levels?
I agree I could just increase ventilation, and that's what I'm doing now. But I recently realized that many extremely-productive people are getting their productivity from using stimulants like caffeine, and so now I'm wondering what other things I could modify in my life to be more productive. I'm just trying to optimize everything.