Glorious glass – worth more than gold?
britishmuseum.org
britishmuseum.org
Obsidian is volcanic glass. We might have also seen glass near meteorite impacts, or perhaps lightning strikes. If not from those natural phenomena, we might have discovered it as a side product of smelting copper, or perhaps some shop's apprentice messing around with the furnace.
My guess is that glass was discovered by someone trying to invent steel making.
You can imagine the sequence of steps: Kids playing with sticks pulling out the red-hot gooey mess. Trying to make the gooey things solidify into interesting shapes. Realising the results are durable and shiny, if a bit ugly in colour. Then experimenting with mixing different kinds of dirt and clay to change the colours. Eventually discovering that translucent is possible, then transparent, etc...