What about taking the override option off noprocrast?
Or, if your concern is simply that YC-funded companies aren't getting work done, you could just lock them out for a couple of hours in the middle of the day. I wouldn't complain about that. :-)
If you think folks spend too much time here, then why not a daily limit? Make noprocrast a fixed limit for everyone.
If you think quality would improve during "open" hours, then why not limit submissions to certain hours? Read-access all the time, but write-access only sometimes.
You could limit the max length of minaway to prevent people from accidentally blocking the site forever. I think max is about 190 years at moment (although if a singularity occured that could become a relevant timespan for procrastinators).