https://www.microchip.com/samples/
https://www.analog.com/en/support/customer-service-resources...
https://reddit.com/r/electronics/comments/1qvcr2/how_to_prop...
Sampling is intended to get a sample so the company's expectation is that it will eventually result in an actual order. This will obviously happen when sampling to companies, and sampling to EE students means those students are more likely to choose your products when they enter the field.
Sampling to hobbyists doesn't really have any return on investment, so once they started getting thousands of requests they just shut it down. These days you are just expected to order low-quantity items from their distributors.
The feedback loop is just very long. Few weeks to get PCB unless you pay a lot extra to get it in few days.
And even if you own a 3d printer for mechanical parts that's still day of printing