IME it's more complicated than that.
Firstly, the NHS allows consultants to do private work, making use of NHS resources, including beds, radiography and theatres. Secondly, a consultant can refer you back to the NHS for treatment, effectively "jumping the queue".
I would never rely on a private hospital. They never have an emergency department, and emergencies happen in hospitals too. Many private hospitals can only treat certain types of case; I wouldn't want to be stuck in a hospital that couldn't treat anything that happened to me.