In 2010, python2.7 was released, backporting a bunch of python3 features. In 2012, python3.3 was released, fixing a bunch of needless incompatibilities. This finally made it viable to support both 2.7 and 3.3 in the same code base. For the most part, the migration of the Python library ecosystem only started in/after 2012.
python3 wasn't really a viable choice for application development until most libraries were ported (2014? 2015?).