By default, all TCP connections should be MPTCP. There is just upside and no real downside. It falls back to TCP when the network doesn't support it, and the vast majority of the internet supports that since iPhones use MPTCP by default.
Please reconsider the decision not to just use MPTCP by default. People using Go software for decades to come will have a buggy experience whenever they move networks from wifi to cell otherwise.