It's actually the JSON parsing. Python is using a highly optimized C parser, whereas Go's json package is in pure Go.
Considering the history of benchmarks, it is quite likely the opposite: The library was selected very carefully, to argue a "point". :-(
* Go, the specification
* gccgo
* 6g and friends: the compilers
"golang" is just the name of the domain and a more searchable term than "go." There is nothing more to it than that.
That and similar type-specific handling could be built into the json package fairly easily, and would make those cases quite a bit faster. Then again, I bet the Go team would have a better and more general idea.