I don't play either WOW or the card game based on it, so I'm wondering, why would you play with cards over the online version?
People who've played lots of Magic say that the WoW card game is a better game than Magic, for what it's worth.
EDIT: Oh, I misread your question. Why? Well, it's sort of like the difference between driving a car and riding a bike. A bike isn't a crappy car, it's fundamentally different, with its own set of strengths.
Also, the collectible card game is NOT a simulation or re-creation of the online game. It's more like Magic set in the WoW universe.