moreover, it would make no sense to own www.pepsi without also already owning www.pepsi.com
But if new TLDs become common I guess that will change with time.
For example how would the Google Chrome browser work (and search to a degree), does a user who types "pepsi" into their omnibar want to go to http://pepsi/ or search for pepsi?
It also adds confusion for webmasters trying to parses URLs on their website. When a user types pepsi.com/coke into their blog for example that link can be made clickable to http://pepsi.com/coke/ where it can't for pepsi/coke