Leave this Mixture in a shallow lid/dish next to the Ant entry point:
1 part borax dish soap
3 parts granulated sugar
15 parts warm water
They will ingest the mixture, and return the payload to the colony if dilute enough. A few days later the slow poison should start to knock out the group.
Indeed, once a path is chemically marked it is very hard to keep ants out, and failure to remove a waste bin lures them in again.
Mixing kiln dried diatomaceous earth with water for treating the surrounding external structure also helps knock down anything with a chitin exoskeleton. It can be effective if a colony has attached to a tunnel system.
Best of luck =)