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I guess my top candidates would be: wikipedia page about google, google stock chart, recent news about google. google.com would never be a result I want to click. The current results are not amazing, but also do we care what the results for that one are? It's like someone telling you "cow" and expecting you'll know the context of what they're thinking of at the moment. Maybe a heading like "I have no idea what you're on about, here are some clickable ideas: google news, google stock price, ..." would be the best solution?
I had multiple people (albeit small sample size) who went to google.com, entered the domain they wanted (e.g. news.ycomb) then clicked the first suggestion which ran the actual search and then clicked on the first hit.
That isn’t to say I hate what this site is doing, I think it is quite neat, but I do think we have to consider that there are more ways used to get to Google than just entering Google.com
It would require an extraordinary circumstance to justify anything else, like if a thing exists, but overwhelmingly the entire net is full of some other reference that is probably what everyone is looking for.
The overwhelming majority of people typing "google" into a search are not looking for the Wikipedia page about google.