if you read documents from that era, the code that they write is wildly alien, because present day programming wasn't invented yet. things that you take for granted just didn't exist. common lisp and to a lesser extent scheme carry all that baggage for backwards compatibility.
so when lisp came out, it didn't have LET, and LET didn't appear until mid 70s. and it was added as a convenience macro for ((lambda (VAR1 VAR2 ...) ...) FORM1 FORM2 ...), which is how people did dynamic binding (also called lambda-binding) for a decade prior. evolution of lisp claims that LET came from lisp machine lisp, but people were independently inventing it all over the place, as a custom macro. depending on how your lambdas were evaluated or how your LET macro was written, you're not just assigning VARs simultaneously, you might not even have a guarantee of the order of evaluation of FORMs. but it got its job done, which is according to revised scheme manual "allowing the forms for the quantities to appear textually adjacent to their corresponding variables". this was a novel convenience at some point!
LET* was invented after LET as a convenience for LET, because sequential binding was even more convenient than binding in general. it would've made sense to then make LET* the "default" of some sort, but the subtle distinction stuck for reasons of legacy code, writing conventions, acquired preferences, and then it got crystalized and preserved for posterity in the common lisp standard.