For large VRAM models, what about selling one of the 3090s, and putting the money towards an NVLink and a motherboard with two x16 PCIe slots (and preferably spaced so you don't need riser cables)?
Though you're right of course that pcie will totally suffice for this case.
p.s. the mobo (B450 Steel Legend) already has 2 pcie x16 slots, so the recommendation does not make sense to me.