The column 'Alumni' compares the number of Nobel prizes or Fields Medals won by Alumni to the number won by Harvard (in percent). Caltech scores 52.8 on this, and ENS 53.4. But Caltech and ENS are by far the smallest of the universities on the top 100 list (unless I am mistaken). Both Caltech and ENS enroll about 200 undergraduates a year, with ENS enrolling only about 100 of those in science and engineering. Caltech has a population of another 1200 graduate students.
One thing to note about Caltech, ENS, and Phystech, they are extremely small, extremely selective, have no legacy admissions, limited or no affirmative action, and pay heavy attention to competitive exams, in the case of ENS and Phystech, administrating them.
That said, Cambridge is a far bigger University than Caltech and others, but a large proportion of those degrees are awarded in non-science fields.
http://nobelprize.org/nobel_prizes/lists/universities.html
Wikipedia has another list based on what universities claim themselves:
http://en.wikipedia.org/wiki/List_of_Nobel_Laureates_by_univ...
So while Caltech is doing very well indeed, there are 15 universities with more affiliated awardees.
The Wiki is the one.