Basically anything that is considered a non-cash benefit is FBT tax owed by the employer. The tax is at the current maximum marginal income tax rate (47%) on a "grossed up" value of the benefit (currently 2.08).
So $1000 of benefit is grossed up to $2080, then taxed at 47% so FBT of $977.60.
Employer can deduct cost of the benefit ($1000) and the FBT ($977.60) from the company's income as an expense. I've left out the complications of GST (VAT) in the example.
There are a bunch of exemptions and stuff (eg for Xmas/end-of-year parties etc) as well as allowable travel expenditure for work etc.
Basically designed to make the fringe benefit not worth giving to employees by employers so that they pay them the cash instead as income.