Ironically, I've been avoiding learning Lua for quite some time for some reason. I guess it's finally time to give it a try!
Its just such a great tool, please don't deny yourself this wonderful experience. Get the VM, put it in something - or find a VM somewhere in something already, and have a lot of fun. And don't forget to make sure you know what a sparse array is, and why pairs() and why ipairs() .. you'll be glad you did!
PS - don't fall for the hype, you can do someTable[0] = "first", someTable[1] = "second" all you like .. :)