How could you have two different languages with the same syntax? The only thing I can think of is one is a subset of the other.
The real question would be whether that AST syntax would be better than the language's own syntax. I'm guessing it would be harder to read, since a good syntax for an AST would describe only the semantics of the tree, making it harder to pick out the structure of the language itself.
edit: I guess what I'm really asking is there someway in lisp to make a construct that would look just like call/cc? If you could then that's just a feature difference, but if you can't I would agree that's a syntactical difference.