https://en.m.wikipedia.org/wiki/Four_color_theorem
I guess maybe I don't understand what you mean by "formally verified setting", but I believe the four color theorem was first proven using a computer.
> Although flawed, Kempe's original purported proof of the four color theorem provided some of the basic tools later used to prove it.
It sounds like Kempe laid some of the groundwork, but then the theorem was ultimately proved using a computer.
I could be wrong though, I'm not an expert in this area.