If you're in the position of doing interviews for the first time, and don't have anybody around to teach you the basics, I would thoroughly recommend getting a copy of Lou Adler's book "Hire With Your Head". It has some really excellent advice on how to approach interviewing, and the hiring process in general.
There's a brief article on Adler's site that covers accomplishment based interviewing that you can find at http://www.adlerconcepts.com/resources/column/interviewing/u....
Having a focus on accomplishment based questions - drilling down into a candidates' experiences on real projects - is a hugely useful technique. Talking about the work in detail helps you separate candidates that interview well from those with real skills.