Screenshots along with text, then use Microsoft Paint to mark up the screen shots. For example, circling the appropriate menu option in a thick red line. Sadly, I do not know how to graphically convey the double-click operation.
Its a time consuming and error prone process, best used if the buggy GUI application is abandonware. Otherwise, the new version will have the same bug or non-intuitive process but the GUI will be unrecognizable. Probably because some manager, somewhere, read too many HN articles and decided a user-facing refactor was the most important thing they could possibly do.