Sorry, mixed things up - store has a limit of one 32-byte store per cycle (load is what has two 32-byte/cycle). Of additional note is Zen 4's tiny store queue of 64 32-byte entries, which could be at play (esp. with it pointing at L3; or it might not be important, I don't know how exactly it interacts with things).

The uiCA link was just to show how out-of-order execution works; the exact timings don't apply as they're for Tiger Lake, not Zen 4. My assertion being that your diagram of spaces between instructions is completely meaningless with OoO execution, as those empty spaces will be filled with instructions from another iteration of the loop or other surrounding code.

Clang is extremely unroll-happy in general; from its perspective, it's ~free to do, has basically zero downsides (other than code size, but noone's benchmarking that too much) and can indeed maybe sometimes improve things slightly.