I have a decent collection of ebooks/pdfs/manga from reading. But I can’t imagine how large a 20TB library is.
That's a safe bet. I'v seen PDF's in the GBs from users treating it like a container format (which it is).
I can't speak for the OP, but you can buy optical media of old out-of-print magazines scanned as PDFs.
I bought the entirety of Desert Magazine from 1937-1985. It arrived on something like 15 CD-ROMS.
I drag-and-dropped the entire collection into iBooks, and read them when I'm on the train.
(Yes, they're probably on archive.org for free, but this is far easier and more convenient, and I prefer to support publishers rather than undermine their efforts.)
There is a significant issue with copyright, though. I'll remove anything with a valid DMCA, but 99.9% of the world's historical magazine issues are now in IP limbo as their ownership is probably unknown. Most of the other .1% aren't overly concerned as distribution is their goal and their main income is advertising, not sales.