You will not be able to get that performance out of Postgres and the write scaling will also be impossible on a non-sharded DB.
If you're a company like Discord and are running dozens (70-something?) of ScyllaDB nodes, likely each with 32 or 64 vCPUs, you've got capacity for 50M+ reads/writes per second across the cluster assuming your read/write workloads are evenly balanced across shards.