Once the information is released, can anyone can make FOIA requests using the schema?
It's not legally protected. An employee could leak it. A public body can voluntarily reveal documents that are exempt from FOIA (absent some other Illinois law prohibiting disclosure). A public body can disclose source code, for instance, despite it being explicitly exempt in the statute. "This data is exempt" is an affirmative defense that the public body has to raise.
"I want your data"
"What data?"
"What do you have?"
"Ha ha. No. Tell me what you want"
"Your data that is the metadata of your data"
"Well actually..."
...
Leave the "Clerk" bit of this out and just imagine you're requesting straight from the IT department. What you can do: get anything not otherwise exempt that they know how to retrieve (it usually helps to provide example commands in the requests). What you cannot do: ask them to go look around and see what they have. That's research. Research is your job, not theirs, under Illinois FOIA.
Again: this is why pulling schemas is so valuable.