"The efficiency numbers aren’t based on calculations or research – I merely ran each circuit in the excellent Lush Projects simulator [SIM] and recorded the numbers it gave me."
I don't want to diss people for writing about stuff as they learn, but I wouldn't take this article too seriously. You can theoretically achieve very high efficiency with basic architectures. The main problem is that you typically also want to make the device small and cheap.
So annoying that a lot of OSHW designs seem to just completely ignore it! It's amazing things work as well as they do!
(A big missing piece here is regulation - all of the test circuits are running open-loop with a 1 kHz square wave switching waveform. Real switching regulators observe the voltage at the output and adjust the switching duty cycle and/or frequency to hit the target voltage.)
The serial boost converter is interesting, I've never seen that topology before - can anyone offer an explanation on how it works?