That's in the normal range of accuracy of modern CO2 sensors, for example SCD40 from Sensirion is described with an accuracy of ±50.0 ppm ±5.0 %m.v.
We do a lot of testing against reference grade sensors and typically see very good performance and reproducibility [1].
[1] https://www.airgradient.com/blog/performance-of-low-cost-co2...
3.6V is the maximum value that the nrf52832 SoC can handle. I would suspect the VDD is variable.