I'm not fully sure of what you means. If we take the following example, are you talking about the neck and the collar of the girl?
https://i.pinimg.com/originals/ea/70/0b/ea700b6a0b366c13187e...
https://fr.pinterest.com/pin/453596993695189968/
I think the name of the concept is "edge control" (not really original). You can find some explanation here
https://www.youtube.com/watch?v=zpSlGmbUB08
To keep it short, there's no line in reality. So while you can use them when sketching, they are pretty crude, kinda like a piano with only 2 keys. The best thing is edges, meaning the delimitation between two contrasting area. If you're doing grayscale, your areas are values (light and shadow) and it's pretty easy. Once you add color, there's more dimension to play with and it became very difficult (warm and cold color, atmospheric colors, brush stroke that gives the illusion of details,...).
Again, this falls under the things that are easy to explain, but take a while to be able to observe it and longer to reproduce it.
There's a book called "Color and Light" by James Gurney that goes in depth about all of these. There's a lot of parameters that goes inside a brush stroke in a specific area of a painting.