> No one is smiling
Don't forget, this was an official photographer mission, sponsored by the Tzar.
I think most people on the photos were stressed enough to be asked to pose in front of unknown equipment, probably with some local officials present on the shoot.
EDIT: actually, there are nice smiling faces on http://www.boston.com/bigpicture/2010/08/russia_in_color_a_c... , where people are not posing.