Plenty of smart people prefer not to try their luck, though. A smart but risk-avoidant person will never be the one to create Facebook either.
There are far, far more external factors on a business's success than internal ones, especially early on.
Dude makes a website in his dorm room and I guess eventually accepts free money he is not obligated to pay back.
What risk?
People from wealthy backgrounds often have less fear of failure, which is a big reason why success disproportionately favors that clique. But frankly, most people in that position are more likely to abuse it or ignore it than to take advantage of it. For people like Zuckerberg and Dell and Gates, the easiest thing to do would have been to slack off, chill out, play their expected role and coast through life... just like most of their peers did.