First of all, keep in mind that research has shown that people generally overestimate the productivity gains of LLM coding assistance. Even when using a coding assistant makes them less productive, they feel like they are more productive.
Second, yeah, experience matters, both with programming and LLM coding assistants. The better you are, the less helpful the coding assistant will be, it can take less work to just write what you want than convince an LLM to do it.
Third, some people are more sensitive to the kind of errors or style that LLMs tend to use. I frequently can't stand the output of LLMs, even if it technically works; it doesn't live to to my personal standards.