proplib (property list library for kernel-userspace communication), RUMP (Rump Kernel - anykernel framework allowing kernel code to run in userspace), Veriexec (verified exec integrity subsystem using cryptographic fingerprints), LFS (Log-structured File System - NetBSD maintains the only production LFS implementation), WAPBL (Write Ahead Physical Block Logging - metadata journaling), ATF (Automated Testing Framework - originated from NetBSD, now used across BSDs), etc. Feel free to check them out! Each one of them is interesting, IMO.
Beyond these specific features, NetBSD's real strength is its extreme portability (runs on over 50 hardware platforms, from VAX to ARM to obscure embedded systems), exceptionally clean and readable codebase, and pkgsrc (a portable package system that works across BSDs, Linux, and other Unix-like systems). I believe it makes NetBSD valuable not just as an OS, but as a reference implementation and research platform. The code quality and documentation are outstanding for anyone studying OS internals as well. :)
I noticed someone asked what NetBSD is. I am happy to break down the different BSD flavors (NetBSD, OpenBSD, FreeBSD, DragonflyBSD) and their unique features if that would be helpful!