Well you can claim that the core is the programming language, in which we write those tax rules, but that's not a very useful distinction IMHO (for how to write programs in the language).
The example on the homepage is the "specific shell" - simple and easy to use, and by far the most common usage, but if you scroll down the table of contents on the API page (https://requests.readthedocs.io/en/latest/api/) you'll see sections titled "Lower-Level Classes" and "Lower-Lower-Level Classes" - that's the generic core, which the upper level is implemented in terms of.
* opinions vary