I don't like how he's measuring accuracy, here. Something that produces (3.149) is treated as closer than (3.139).
22/7 looks marginally better, if we compare actual error. It's the same number of characters as 3.14, but about 20% less error. 355/113, meanwhile, is not only better than 3.14159 (same number of characters) but actually even better than 3.141592 (about 60% less error).
It's also easier to remember, due to the repeated digits.