Can you find any three-cabin service where First class is the middle tier of cabin? (In a two-cabin service, whether the one that's not economy is called Business or First is not helpful in determining whether business or first is higher; we both agree they're better than economy.)
Here are airlines offering three-cabin services on a single aircraft where First is the highest tier:
Air France - La Première (First), Business, Economy
American Airlines - First, Business, Economy
Cathay Pacific - First, Business, Economy
Emirates - First Class suites, Business Class, and Economy
Etihad - First Class private suites, Business, Economy
Japan Airlines - First, Business, Economy
Lufthansa - First, Business, Economy