It's even more complex than that. If Ukraine responded conventional war with nukes, it can be sure Russia would retaliate with even more nukes, practically extinguishing their statehood.
The equilibrium is reached when the exchange is equally devastating, so the only winning move is attacking first, and only if the attacked won't be able to retaliate. The Cold War never ended, just warmed a little, because it doesn't exist (yet) a guaranteed way to avoid an all-out nuclear retaliation.