C++ destructors are implicit, while defer is explicit.

You can just look at the code in front of you to see what defer is doing. With destructors, you need to know what type you have (not always easy to tell), then find its destructor, and all the destructors of its parent classes, to work out what's going to happen.

Sure, if the situation arises frequently, it's nice to be able to design a type that "just works" in C++. But if you need to clean up reliably in just this one place, C++ destructors are a very clunky solution.