That's a pretty interesting angle. But it might be a bridge too far. Gamers would almost certainly follow Valve to Linux. But asking them to give up their mp3 players, chat programs and background tasks while they're gaming?
Only if it were a living room solution, which has its own "day 1" sorts of challenges. (e.g. the number of titles with not only gamepad support, but where you truly do not need the keyboard/mouse to play.)