Value stacks are something I heard about in a "Marriage and Family" class in college where the professor discussed that if you value say "economy" more than "time", you spend a lot of time to save a few cents, but if you reverse that stack order your spend extra cents to avoid spending the time. If the person you're dating has a very different stack than you do, it will be a source of problems going forward and doesn't suggest you'll have a successful marriage.
Playing video games together should certainly be a way to get a handle on how someone's values stack up relative to yours.