The constant problem is that "big scale" always means "larger than I've seen", so on any project larger than a person has encountered, they assume they need to pull out the big guns. Also, people worry about things like what happens if they really *do* scale 10 years from now.
Neither is a practical concern for nearly anyone who will ever face this decision.
And then yes, of course, some people have problems that actually can't be solved by Postgres. But verify this first, don't assume.