For evidence see, well, all the other institutions of the US federal government.
Edit: forgot to say, Mir cards used to work in a few other countries, for example, Turkey and Armenia. But eventually the US government pressured the banks in those countries to stop accepting Mir, because apparently that would somehow help defeat Putin or something.
This way, there is always a threat of businesses deciding not to do business with you by unaccountable forces.
Visa/Mastercard vs the government itself is bordering on a distinction without a difference.
From the perspective of the average business or person they're both wholly unaccountable.
If you're Kickstarter or some Megacorp, well then it probably just depends which you have more friends in high places.