It's true that LLMs do something that looks very compression like in their weights, but it is lossy, and it has to be--if you're not lossy, you've overfitted the corpus, and that's bad. Post-training takes this even further, because you're not doing anything that looks like training on a specific corpus, you're exploring in a wider space of text. That text doesn't even concretely exist until you start exploring it.
I'm sure there must be a serious attempt to pursue this analogy that isn't just handwaving, but I haven't seen it.