After they get it when they are authorized to get it. You cannot point at random things and call them evidence. For instance, I can take a dump and flush it, despite law enforcement's assertion that my stool is evidence in some imaginary crime.
The textbook tampering with evidence example is: drug dealer tries to flush the drugs when the police knock on the door.
But yeah, people tamper with evidence because they think they can get away with it. That doesn’t mean they always succeed in cleanly doing it without creating evidence of the tampering itself.