Apple Card is the result of a co-branding deal between Apple and Goldman Sachs (which is currently in the process of exiting the deal and being replaced in that capacity by JPMorgan Chase). Apple provides the branding and some minor fintech features; Goldman (or in the future Chase) issues the card and is on the hook if people don't pay their credit card bill.
Presumably for this particular program using Klarna was cheaper because Klarna already specializes in precisely this kind of transaction.