DNS based adblockers have strictly worse adblocking capabilities than manifest v3 adblockers. I mean, sure they have their uses (eg. blocking ads/telemetry in apps or whatever), but bringing them up in this context doesn't really make sense.
Running unbound or a pi-hole on your network doesn't preclude that.
Your devices talks to the gateway/router/pi-hole on the network, who will then use your chosen DoH providers for upstream requests.
No. See:
https://developer.chrome.com/docs/extensions/reference/api/d...
>The chrome.declarativeNetRequest API is used to block or modify network requests by specifying declarative rules. This lets extensions modify network requests without intercepting them and viewing their content, thus providing more privacy.