"Not available yet", at least to me, carries the implication that it will, not just might, become available at some point. Probably soon enough that it's worth asking the question again later. Whereas "don't know" suggests that it's not worth asking the question again, because you're probably just going to get "don't know" as the answer. (At least, if "don't know" and "not available yet" are both presented as options).