"Turning off your brain" is a very condescending way to refer to people with skills you don't possess or understand.
(To borrow terminology from "Thinking, Fast and Slow"):
In my experience, more socially-inclined people are able to rely easily on System 1 -- whereas the more awkward ("engineer" types) attempt to engage System 2 continually, and thus the experience of talking with them often feels effortful and lacking in "flow."
EDIT: A quick primer, from Wikipedia (http://en.wikipedia.org/wiki/Thinking,_Fast_and_Slow#Two_sys...)
"In the book's first section, Kahneman describes the two different ways the brain forms thoughts:
System 1: Fast, automatic, frequent, emotional, stereotypic, subconscious
System 2: Slow, effortful, infrequent, logical, calculating, conscious"