On a purely technical basis, the most common, honest answer is "no." There are no inherent properties of LLMs that would make them independently turn computers into death machines. That's all humans, no matter how you dress it up.
There is, however, the hubris (human) problem. The rhetorical, experimental, and financial irresponsibility around this tech's roll out is far greater a threat to humanity than the actual technology itself.
And frankly that's a shame because LLMs are a phenomenal tool. But the Hollywood shit has cooked people's brains to the point of absurdity.